Chelation of a proton by an aliphatic tertiary diamine.

Single operation palladium catalysed C(sp3)-H functionalisation of tertiary aldehydes: investigations into transient imine directing groups.

Simple amine and diamine derivatives can promote the palladium catalysed direct β-C-H arylation of aliphatic aldehydes via transient imine formation. Trifluoroacetate was shown to be crucial in promoting the reaction. Sub-stoichiometric quantities of simple N-tosylethylenediamine was shown to form a bidentate directing group with an imine linkage. Isolation of an unsymmetrical palladacycle has ...

Ultrasonic Properties in Bisphenol A-based Thermosets Cured with Mna and Aliphatic Diamine

Conformational Study of some novel Methoxy Half-Analogues of Michler’s Ketone by NMR

One series of half-analogues of Michler’s ketone containing one or more terminal methoxysubstituents with variable tertiary amino groups have been used in this study. NMR spectralresults for the parent ketones confirm earlier findings that ortho proton shifts are apparentlyindependent from steric effects in derivatives of Michler’s ketone because the ring current andcarbonyl-induced shifts are ...

Synthesis and Characterization of Novel Photoactive ‎Poly(ether-amide)s Based on Highly Substituted ‎Phenanthrimidazole

A new aromatic diamine monomer containing ether linkage based on the phenanthrimidazole ring, ‎1,1´-(4,4´- oxy bis(1,4-phenylene))bis(2-(4-aminophenyl)-1H-phenanthro[9,10-d]imidazole) was synthesized through four-‎components condensation of 4,4´-diamino diphenyl ether, 4-nitrobenzaldehyde, phenanthrene-9,10-dione and ammonium ‎acetate in presence of acetic acid, followed by palladi...

Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines† †Electronic supplementary information (ESI) available: Full experimental details for catalytic procedures and characterization data. See DOI: 10.1039/c6sc02129h Click here for additional data file.

A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C–H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C–H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated a-olefins. This work represents the...